Email this article 
Europium Complexes with Fluorinated Carbazole-Containing Tetraketones
- Authors: Shubina A.G.1, Kostryukova T.S.2, Pugachev D.E.2, Paramonov D.V.2, Vatsadze S.Z.3, Vasilyev N.V.1,2
-
Affiliations:
- State University of Education
- State Research Institute of Biological Instrumentation
- Zelinsky Institute of Organic Chemistry
- Issue: Vol 95, No 3-4 (2025)
- Pages: 121-130
- Section: Articles
- URL: https://freezetech.ru/0044-460X/article/view/686619
- DOI: https://doi.org/10.31857/S0044460X25030061
- EDN: https://elibrary.ru/DDPWCJ
- ID: 686619
Cite item
Open Access
Access granted
Abstract
Complex compounds of fluorine-containing tetraketones on the basis of carbazole with europium(III) ions were synthesized, the luminescence-spectral properties of the obtained complexes were evaluated and the exact stoichiometric composition was established. The position of the maximum in the excitation spectrum (≥ 370 nm) of the complexes, a significant Stokes shift (> 250 nm), and a long lifetime of the excited state (400–700 μs) allow us to consider the synthesized complexes as potential reagents for time-resolved fluorescence immunoassay.
Full Text
About the authors
Anna G. Shubina
State University of Education
Author for correspondence.
Email: shubina.anna98@yandex.ru
ORCID iD: 0009-0004-7466-5037
Russian Federation, Moscow
Tatiana S. Kostryukova
State Research Institute of Biological Instrumentation
Email: shubina.anna98@yandex.ru
Russian Federation, Moscow
Dmitry E. Pugachev
State Research Institute of Biological Instrumentation
Email: shubina.anna98@yandex.ru
ORCID iD: 0000-0002-2042-3911
Russian Federation, Moscow
Dmitry V. Paramonov
State Research Institute of Biological Instrumentation
Email: shubina.anna98@yandex.ru
ORCID iD: 0009-0009-8005-8504
Russian Federation, Moscow
Sergey Z. Vatsadze
Zelinsky Institute of Organic Chemistry
Email: shubina.anna98@yandex.ru
ORCID iD: 0000-0001-7884-8579
Russian Federation, Moscow
Nikolay V. Vasilyev
State University of Education; State Research Institute of Biological Instrumentation
Email: shubina.anna98@yandex.ru
ORCID iD: 0000-0003-4146-3979
Russian Federation, Moscow; Moscow
References
- Пат. 2296756 (2007) // ГосНИИ БП. 2007. RU2296756 C2.
- Pugachov D.E., Kostryukova T.S., Zatonsky G.V., Vatsadze S.Z., Vasil’ev N.V. // Chem. Heterocycl. Compd. 2018. Vol. 54. N 5. P. 528. doi: 10.1007/s10593-018-2300-4
- Пугачев Д.Е., Кострюкова Т.С., Ивановская Н.П., Лямин А.И., Романов Д.В., Моисеев С.В., Затонский Г.В., Осин Н.С., Васильев Н.В. // ЖОХ. 2019. Т. 89. № 5. С. 779; Pugachyov D.E., Kostryukova T.S., Ivanovskaya N.P., Lyamin A.I., Romanov D.V., Moiseyev S.V., Zatonskii G.V., Osin N.S., Vasilyev N.V. // Russ. J. Gen. Chem. 2019. Vol. 89. P. 965. doi: 10.1134/S1070363219050165
- Кострюкова Т.С., Ивановская Н.П., Затонский Г.В., Осин Н.С., Васильев Н.В. // Биоорг. хим. 2015. Т. 41. № 2. С. 212; Kostryukova T.S., Ivanovskaya N.P., Zatonskii G.V., Osin N.S., Vasil’ev N.V. // Russ. J. Bioorg. Chem. 2015. Vol. 41. N 2. P. 186. doi: 10.1134/S1068162015010094
- Pugachev D.E., Zatonsky G.V., Kostryukova T.S., Shubina A.G., Vasiliev N.V. // Int. J. Org. Chem. 2024. Vol. 14. N 1. P. 20. doi: 10.4236/ijoc.2024.141002
- Пат. 2709194 (2019) // ГосНИИ БП. 2019. RU2709194 C1.
- He P., Wang H., Liu S., Hu W., Shi J., Wang G., Gong M. // J. Electrochem. Sci. 2009. Vol. 156. N 2. P. E46. doi: 10.1149/1.3042206
- Liu S.G., Su W.Y., Pan R.K., Zhou X.P. // Chin. J. Chem. Phys. 2012. Vol. 25. N 6. P. 697. doi: 10.1088/1674-0068/25/06/697-702
- He P., Wang H.H., Yan H.G., Hu W., Shi J.X., Gong M.L. // Dalton Trans. 2010. Vol. 39. P. 8919. doi: 10.1039/c0dt00424c
- White J.G. // Inorg. Chim. Acta. 1976. Vol. 16. P. 159. doi: 10.1016/S0020-1693(00)91705-5
- Binnemans K. // Handbook on the Physics and Chemistry of Rare Earth. 2005. Vol. 35. P. 107. doi: 10.1016/S0168-1273(05)35003-3
- Тайдаков И.В., Зайцев Б.Е., Лобанов А.Н., Витухновский А.Г., Дацкевич Н.П., Селюков А.С. // ЖНХ. 2013. Т. 58. № 4. С. 473; Taidakov I.V., Zaitsev B.E., Lobanov A.N., Vitukhnovskii A.G., Datskevich N.P., Selyukov A.S. // Russ. J. Inorg. Chem. Vol. 58. P. 411. doi: 10.1134/S0036023613040190
- Кострюкова Т.С., Логинова О.Д., Васильев Н.В. // Вестн. Моск. гос. обл. унив. 2014. Т. 5. С. 80.
- Valta T., Puputti E.M., Hyppänen I., Kankare J., Takalo H., Soukka T. // Anal. Chem. 2012. Vol. 84. N 18. P. 7708. doi: 10.1021/ac3008913
- Gordon A.J., Ford R.A. The Chemist’s companion. New York; London; Sydney; Toronto: Wiley-Interscience Publication, 1972. 537 p.
Supplementary files
