Functional derivatization of 3- and 5-substituted cyclooctenes

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Resumo

New derivatives of cyclooctene with an ester group in the 3- and 5-positions have been synthesized in high yield. The structure of obtained compounds was confirmed by a complex of physicochemical methods. The products are of interest as monomers for the synthesis of hydrophilic and amphiphilic homo- and copolymers using ring-opening metathesis polymerization of olefins. Owing to the unsaturated backbone, such polymers can undergo further modification, including by the reaction of macromolecular cross-metathesis.

Sobre autores

O. Adzhieva

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: finko.alexander@gmail.com

A. Finko

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences;Moscow State University

Email: finko.alexander@gmail.com

A. Roenko

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: finko.alexander@gmail.com

Yu. Denisova

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: finko.alexander@gmail.com

Y. Kudryavtsev

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: finko.alexander@gmail.com

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