Dielectric Properties of Graphite Oxide Polymeric Composites Based on N-Vinylpirrolidone Copolymers with Different Topologies

G. V. Simbirtseva; Симбирцева Г. В.; C. D. Babenko; Бабенко С. Д.; E. O. Perepelitsina; Перепелицина Е. О.; P. I. Komendant; Комендант Р. И.; S. V. Kurmaz; Курмаз С. В.

doi:10.31857/S0044453723010302

Dielectric Properties of Graphite Oxide Polymeric Composites Based on N-Vinylpirrolidone Copolymers with Different Topologies

Authors: Simbirtseva G.V.¹, Babenko C.D.¹, Perepelitsina E.O.¹, Komendant P.I.¹, Kurmaz S.V.¹
Affiliations:
1. Institute of Problems of Chemical Physics, Russian Academy of Sciences
Issue: Vol 97, No 1 (2023)
Pages: 175-182
Section: ЭЛЕКТРОХИМИЯ. ГЕНЕРАЦИЯ И АККУМУЛИРОВАНИЕ ЭНЕРГИИ ИЗ ВОЗОБНОВЛЯЕМЫХ ИСТОЧНИКОВ
Submitted: 27.02.2025
Published: 01.01.2023
URL: https://freezetech.ru/0044-4537/article/view/668898
DOI: https://doi.org/10.31857/S0044453723010302
EDN: https://elibrary.ru/BDGVJY
ID: 668898

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Abstract

The dielectric properties of graphite oxide composite materials based on a biocompatible branched copolymer of N-vinylpyrrolidone with 1,6-hexanediol dimethacrylate and a cross-linked copolymer of N‑vinylpyrrolidone with triethylene glycol dimethacrylate are studied. High-frequency (9.8 GHz) and low-frequency (25 Hz–1 MHz) measurements of the complex permittivity and electrical conductivity of polymer composites are carried out and their dependences on the polymer matrix topology and formation conditions are analyzed. Copolymers and composites based on them are characterized by IR, UV, and visible spectroscopy, dynamic light scattering, and the surface morphology of nanocomposite polymer matrices is characterized by optical microscopy. It is shown that the proposed electrophysical approach makes it possible to additionally characterize polymer matrices with carbon nanofillers.

Keywords

polymer composites, graphite oxide, complex permittivity electrical, conductivity

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