Microwave Synthesis of Nickel-Based Catalysts for Selective Hydrogenation of Phenylacetylene to Styrene

V. S. Zhuravleva; Журавлева В. С.; A. A. Shesterkina; Шестеркина А. А.; A. A. Strekalova; Стрекалова А. А.; G. I. Kapustin; Капустин Г. И.; S. F. Dunaev; Дунаев С. Ф.; A. L. Kustov; Кустов А. Л.

doi:10.31857/S004445372310028X

Microwave Synthesis of Nickel-Based Catalysts for Selective Hydrogenation of Phenylacetylene to Styrene

Авторлар: Zhuravleva V.S.¹^,2, Shesterkina A.A.³, Strekalova A.A.¹, Kapustin G.I.¹, Dunaev S.F.³, Kustov A.L.³
Мекемелер:
1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
2. Russian Technological University MIREA
3. Faculty of Chemistry, Moscow State University
Шығарылым: Том 97, № 10 (2023)
Беттер: 1415-1420
Бөлім: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
##submission.dateSubmitted##: 26.02.2025
##submission.datePublished##: 01.10.2023
URL: https://freezetech.ru/0044-4537/article/view/668639
DOI: https://doi.org/10.31857/S004445372310028X
EDN: https://elibrary.ru/PPNDUP
ID: 668639

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Аннотация

New nickel-containing catalysts based on the phyllosilicate phase have been obtained by microwave activation for efficient liquid-phase hydrogenation of a number of unsaturated compounds to olefins under relatively mild reaction conditions: T = 100–140°C, pH2 = 1.5 MPa, reaction time 1 h. A comparison of the synthesis methods showed that the best results with 90.1% selectivity of styrene formation at 89.6% conversion of phenylacetylene were obtained on the nickel catalyst prepared by microwave synthesis.

Негізгі сөздер

Ni/SiO2 catalysts, selective hydrogenation, phenylacetylene, microwave synthesis, monometallic nanoparticles

Әдебиет тізімі

Yang K., Chen X., Guan J. et al. // Catal. Today. 2015. V. 246. P. 176.
Molnár Á., Sárkány A., Varga V. // Mol. Cat. A. Chem. 2001. V. 173. P. 185.
Bonrath W., Medlock J., Schütz J. et al. // Hydrogenation. 2012. P. 66.
Kluwer A.M., Koblenz T.S., Jonishkeit T. et al. // Am. Chem. Soc. 2005. V. 127. P. 15470.
Rahsepar M., Kim H. // J. Alloys Compd. 2015. V. 649. P. 1323.
Redina E.A., Greish A.A., Mishin I.V. et al. // Catal. Today. 2015. V. 241. P. 246.
Beletskaya I.P., Kustov L.M. // Russ. Chem. Rev. 2010. V. 79 (6). P. 441.
Sels B.F., Kustov L.M. // Zeolites and Zeolite-like Materials 2016. P. 1.
Manjunatha C., Ashoka S., Hari Krishna R. Chapter 1 – Microwave-assisted Green Synthesis of Inorganic Nanomaterials, Green Sustainable Process for Chemical and Environmental Engineering and Science. 2021. P. 1.
Bian Z., Kawi S. // Catal. Today. 2020. V. 339. P. 3.
Wang M.L., Ban X.Q., Xie L.Q. et al. // ACS Sustain. Chem. Eng. 2019. V. 7. P. 1989.
Yu J., Yang Y.S., Chen L.F. et al. // Appl. Catal. B: Environ. 2020. V. 277. 119273.
Wang Y.L.H. // Chem. Phys. Lett. 2020. V. 757. 137871.
Aguilar-Tapia A., Delannoy L., Loui C. et al. // J. Catal. 2016. V. 344. P. 515.
Narani A., Kannapu H.P.R., Natte K. et al. // Mol. Catal. 2020. V. 497. 111200.
Kirichenko O., Kapustin G., Nissenbaum V. et al. // J. Therm. Anal. Calorim. 2018. V. 134. P. 233.
Kirichenko O., Kapustin G., Nissenbaum V. et al. // J. Therm. Anal. Calorim. 2014. V. 118. P. 749.
H. Liu, H. Wang, J. Shen, Y. Sun and Z. Liu // Applied Catalysis A: General, https://doi.org/10.1016/j.apcata.2007.12.006