Stability Constants of Nickel(II) Complexes with [2.2.2]Cryptand in Aqueous Ethanol Solutions

V. A. Isaeva; Исаева В. А.; E. I. Pogodina; Погодина Е. И.; A. S. Katolikova; Католикова А. С.; V. A. Sharnin; Шарнин В. А.

doi:10.31857/S0044453723040155

Stability Constants of Nickel(II) Complexes with [2.2.2]Cryptand in Aqueous Ethanol Solutions

Autores: Isaeva V.A.¹, Pogodina E.I.¹, Katolikova A.S.¹, Sharnin V.A.¹
Afiliações:
1. Ivanovo State University of Chemistry and Technology
Edição: Volume 97, Nº 4 (2023)
Páginas: 505-511
Seção: ФИЗИЧЕСКАЯ ХИМИЯ РАСТВОРОВ
##submission.dateSubmitted##: 27.02.2025
##submission.datePublished##: 01.04.2023
URL: https://freezetech.ru/0044-4537/article/view/668757
DOI: https://doi.org/10.31857/S0044453723040155
EDN: https://elibrary.ru/TFXMBE
ID: 668757

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Resumo

The stability constants of nickel(II) complexes with [2.2.2]cryptand in aqueous ethanol solutions with a variable concentration of the organic co-solvent were determined by potentiometry at Т = 298 K and µ → 0. It was found that mononuclear, binuclear, and protonated nickel(II) cryptates can form in solution, whose stability increases with the ethanol content. The Gibbs energies of nickel(II) ion transfer from water to the aqueous ethanol solvent were calculated using published data. The contributions of resolvation of reagents in water–ethanol mixtures to the change in the stability of nickel(II) complexes with [2.2.2]cryptand were evaluated.

Palavras-chave

[2.2.2]cryptand, nickel(II) ion, complexation, stability constant, aqueous ethanol solvent

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