High-temperature synthesis of cobalt nanoparticles in hyperbranched polyester polyol medium

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Abstract

The synthesis of CoNPs cobalt nanoparticles by the method of polyol- process was proposed, which consists in a high-temperature synthesis of polymer-stabilized metal nanoparticles in a matrix of a fourth-generation hyperbranched polyester polyol. Branched polyester polyol acts as both a reducing agent and a stabilizer at the same time. It has been found that the reduction of the precursor CoCl2 with a hyperbranched polyester polyol occurs at 210°C. The introduction of NaOH into the reaction mixture makes it possible to lower the synthesis temperature by 50°C and leads to a change in the mechanism of in situ ripening CoNPs from the digestive mechanism to direct Ostwald ripening.

About the authors

M. P Kutyreva

Kazan Federal University, Butlerov Chemistry Institute

Email: mkutyreva@mail.ru

A. E Burmatova

Kazan Federal University, Butlerov Chemistry Institute

A. A Khannanov

Kazan Federal University, Butlerov Chemistry Institute

V. G Evtugin

Kazan Federal University, Butlerov Chemistry Institute

References

  1. Fievet F., Lagier J., Blin B., Beaudoin B., Figlarz M. // Solid State Ion. 1989. Vol. 32-33. P. 198. doi: 10.1016/0167-2738(89)90222-1
  2. Mourdikoudis S. Reducing agents in colloidal nanoparticle synthesis. The Royal Society of Chemistry, 2021. 482 p. doi: 10.1039/9781839163623
  3. Liu Q., Cao X., Wang T., Wang C., Zhang Q., Ma L. // RSC Adv. 2015. Vol. 5. N 7. P. 4861. doi: 10.1039/c4ra13395a
  4. Takahashi K., Yokoyama S., Matsumoto T., Cuya Huaman J.L., Kaneko H., Piquemal J.Y., Miyamura H., Balachandran J. // New J. Chem. 2016. Vol. 40. N 10. P. 8632. doi: 10.1039/c6nj01738j
  5. Eluri R., Paul B. // Mater. Lett. 2012. Vol. 76. P. 36. doi: 10.1016/j.matlet.2012.02.049
  6. Silvert P.Y., Herrera-Urbina R., Duvauchelle N., Vijayakrishnan V., Elhsissen K.T. // J. Mater. Chem. 1996. Vol. 6. N 4. P. 573. doi: 10.1039/JM9960600573
  7. Soumare Y., Garcia C., Maurer T., Chaboussant G., Ott F., Fiévet F., Piquemal J.Y., Viau G. // Adv. Funct. Mater. 2009. Vol. 19. N 12. P. 1971. doi: 10.1002/adfm.200800822
  8. Joseyphus R.J., Shinoda K., Kodama D., Jeyadevan B. // Mater. Chem. Phys. 2010. Vol. 123. N 2-3. P. 487. doi: 10.1016/j.matchemphys.2010.05.001
  9. Couto G.G., Klein J.J., Schreiner W.H., Mosca D.H., Zarbin A.J.G. // J. Colloid Interface Sci. 2007. Vol. 311. N 2. P. 461. doi: 10.1016/j.jcis.2007.03.045
  10. Wu S.H., Chen D.H. // J. Colloid Interface Sci. 2003. Vol. 259. N 2. P. 282. doi: 10.1016/S0021-9797(02)00135-2
  11. Yang H., Shen C., Song N., Wang Y., Yang T., Gao H., Cheng Z. // Nanotechnology. 2010. Vol. 21. N 37. P. 375602. doi: 10.1088/0957-4484/21/37/375602
  12. Izu N., Matsubara I., Uchida T., Itoh T., Shin W. // J. Ceram. Soc. Japan. 2017. Vol. 125. N 9. P. 701. doi: 10.2109/jcersj2.17114
  13. Žagar E., Žigon M. // Prog. Polym. Sci. 2011. Vol. 36. N 1. P. 53. doi: 10.1016/j.progpolymsci.2010.08.004
  14. Zheng Y., Li S., Weng Z., Gao C. // Chem. Soc. Rev. 2015. Vol. 44. N 12. P. 4091. doi: 10.1039/c4cs00528g
  15. Khannanov A.A., Rossova A.A., Ignatyeva K.A., Ulakhovich N.A., Gerasimov A.V., Boldyrev A.E., Evtugyn V.G., Rogov A.M., Cherosov M.A., Gilmutdinov I.F., Kutyreva M.P. // J. Magn. Magn. Mater. 2021. P. 168808. doi: 10.1016/j.jmmm.2021.168808
  16. Medvedeva O.I., Kambulova S.S., Bondar O.V., Gataulina A.R., Ulakhovich N.A., Gerasimov A.V., Evtugyn V.G., Gilmutdinov I.F., Kutyreva M.P. // J. Nanotechnol. 2017. Vol. 2017. P. 1. doi: 10.1155/2017/7607658
  17. Joseyphus R.J., Matsumoto T., Takahashi H., Kodama D., Tohji K., Jeyadevan B. // J. Solid State Chem. 2007. Vol. 180. N 11. P. 3008. doi: 10.1016/j.jssc.2007.07.024
  18. Aranishi K., Zhu Q-L., Xu Q. // ChemCatChem. 2014. Vol. 6. N 5. P. 1375. doi: 10.1002/cctc.201301006
  19. Alrehaily L.M., Joseph J.M., Biesinger M.C., Guzonas D.A., Wren J.C. // Phys. Chem. Chem. Phys. 2013. Vol. 15. N 3. P. 1014. doi: 10.1039/c2cp43094k
  20. Karahan S., Özkar S. // Int. J. Hydrog. Energy 2015. Vol. 40. N 5. P. 2255. doi: 10.1016/j.ijhydene.2014.12.028
  21. Преч Э., Бюльманн Ф., Аффольтер К. Определение строения органических соединений. Таблицы спектральных данных. М.: Мир; БИНОМ, Лаборатория знаний, 2006. 438 с. doi: 10.1007/978-3-662-04201-4
  22. Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. John Wiley & Sons, Inc., 2009. doi: 10.1002/9780470405840
  23. Практикум по органической химии / Под ред. Г. Беккера. М.: Мир, 1979. Т. 1. 454 с.

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