Inclusion Complex of Gd(III) with β-Cyclodextrin and L-Tryptophan

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Abstract

An inclusion complex of gadolinium(III) with L-tryptophan (Trp) and β-cyclodextrin (β-CD) with the composition Gd(Trp)3Cl3∙3β-CD∙nH2O was synthesized. It was established that the complex is formed due to the entry of the aromatic part of the L-Trp molecule into the β-CD cavity, and the Gd3+ ions are located in the outer sphere.

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About the authors

S. S. Khasaeva

Kuban State University

Author for correspondence.
Email: justchemist@mail.ru
ORCID iD: 0000-0002-8462-8801
Russian Federation, Krasnodar, 350040

N. N. Bukov

Kuban State University

Email: justchemist@mail.ru
ORCID iD: 0000-0001-8559-110X
Russian Federation, Krasnodar, 350040

S. N. Ivanin

Kuban State University

Email: justchemist@mail.ru
ORCID iD: 0000-0001-9352-5970
Russian Federation, Krasnodar, 350040

S. L. Kuznetsova

Kuban State University

Email: justchemist@mail.ru
ORCID iD: 0009-0000-8868-0730
Russian Federation, Krasnodar, 350040

E. L. Isaeva

Chechen State University named after A. A. Kadyrov

Email: justchemist@mail.ru
ORCID iD: 0000-0001-8403-5240
Russian Federation, Grozny, 364024

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Supplementary files

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2. Fig. 1. Thermogram of the β-cyclodextrin inclusion complex with gadolinium(III) and L-tryptophan.

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3. Fig. 2. IR spectra of GdTrp, β-CD, inclusion complex (GdTrp/β-CD).

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4. Fig. 3. Schematic representation of a fragment of the proposed inclusion complex.

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5. Fig. 4. Diffractogram of the inclusion complex (GdTrp/β-CD), β-CD, Trp, GdCl3×6H2O.

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6. Fig. 5. EPR spectrum of the Gd(Trp)3Cl3*3β-CD*nH2O inclusion complex.

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