Synthesis and heterocyclization reaction of tribenzylbenzene sulfonylimino chloride with various polarophiles

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Abstract

A new method has been developed for the preparation of multifunctional pyrazoles by the reaction of 1,3-dipolar addition of tribenzylsulfonyliminochloride to polarophiles. This imine was obtained by reacting tribenzylamine with N -chlorobenzenesulfamide (chloramine-B). Regardless of the structure and composition of polarophiles, the cyclization reaction takes place in the presence of alkali for 6-8 h of boiling, which proves the activation of the methylene groups of tribenzylamine with the help of an electron-withdrawing sulfamide group.

About the authors

A. A Makhmudova

Institute of Chemistry of Additives named after A.Kuliyev of the National Academy of Sciences of Azerbaijan

Email: iradam@rambler.ru

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