On the kinetics of crystallization of the free and contact sides of Fe77Ni1Si9B13 amorphous alloy ribbons at low-temperature annealing

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Abstract

The differences between the kinetics of crystallization of the free and contact sides of the ribbon of the amorphous Fe77Ni1Si9B13 alloy at 400°C were considered. As a result of X-ray phase analysis, it was found that crystals based on α-Fe were formed on the contact side even after annealing for 5 min. In the case of the free side, reflections related to α-Fe crystals could be detected on the free side only after annealing for 30 min. The relative content of the crystalline phase was determined from X-ray diffraction data using the relationship between the integral intensity of the reflection of the analyzed phase and its volume fraction. Possible reasons for the observed differences in crystallization were considered. Crystallization in the near-surface layers of both the contact and free sides of the ribbon was shown to occur in two stages (isotropic growth of existing nuclei at a decreasing rate of crystal nucleation and slow anisotropic growth of already formed crystals). The first stage was satisfactorily described within the framework of the Johnson–Mel–Avrami–Kolmogorov thermodynamic formalism, but for the second stage it was unlawful to apply the kinetic equation.

About the authors

М. S. Konovalov

Scientific Center for Metallurgical Physics and Materials Science of Udmurt Federal Research Center of the Ural Branch RAS

Author for correspondence.
Email: maksim.kov@mail.ru
Russian Federation, Izhevsk

V. I. Lad’yanov

Scientific Center for Metallurgical Physics and Materials Science of Udmurt Federal Research Center of the Ural Branch RAS

Email: maksim.kov@mail.ru
Russian Federation, Izhevsk

М. I. Mokrushina

Scientific Center for Metallurgical Physics and Materials Science of Udmurt Federal Research Center of the Ural Branch RAS

Email: maksim.kov@mail.ru
Russian Federation, Izhevsk

А. А. Suslov

Scientific Center for Metallurgical Physics and Materials Science of Udmurt Federal Research Center of the Ural Branch RAS

Email: maksim.kov@mail.ru
Russian Federation, Izhevsk

А. I. Shilyaev

Scientific Center for Metallurgical Physics and Materials Science of Udmurt Federal Research Center of the Ural Branch RAS

Email: maksim.kov@mail.ru
Russian Federation, Izhevsk

S. А. Tereshkina

Scientific Center for Metallurgical Physics and Materials Science of Udmurt Federal Research Center of the Ural Branch RAS

Email: maksim.kov@mail.ru
Russian Federation, Izhevsk

V. B. Ivanov

Scientific Center for Metallurgical Physics and Materials Science of Udmurt Federal Research Center of the Ural Branch RAS

Email: maksim.kov@mail.ru
Russian Federation, Izhevsk

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