Effect of Phosphorus-Containing Dispersant on the Microstructure and Optical Properties of Scintillation Ceramic (Gd, Y)3(Al, Ga)5O12:Ce with Garnet Structure
- Authors: Karpyuk P.V.1, Ermakova L.V.1, Dubov V.V.1, Lelekova D.E.1, Saifutyarov R.R.1, Zhdanov P.A.1, Malozovskaya M.S.1, Komendo I.Y.1, Sokolov P.S.1, Bondarau A.G.2, Korzhik M.V.2
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Affiliations:
- National Research Center “Kurchatov Institute”
- Institute for Nuclear Problems, Belarus State University
- Issue: No 8 (2024)
- Pages: 123-132
- Section: Articles
- URL: https://freezetech.ru/1028-0960/article/view/664770
- DOI: https://doi.org/10.31857/S1028096024080156
- EDN: https://elibrary.ru/EKLKIP
- ID: 664770
Cite item
Abstract
Phosphoric acid ester, a typical component of commercial dispersants, affects the functional properties of Gd1.494Y1.494Ce0.012Al2Ga3O12 ceramics. In sintered ceramics, the residual phosphorus can reach up to 40–70% of the introduced amount. The admixture of phosphorus located on the surfaces of the particles activates the grain growth during sintering and leads to the formation of secondary phases of rare-earth phosphates. With increasing phosphorus concentration, the density and optical transmittance of ceramics decrease. Relatively small amount of phosphorus can improve the luminescence properties of ceramics, but large amounts can increase phosphorescence and reduce the scintillation light yield.
Keywords
About the authors
P. V. Karpyuk
National Research Center “Kurchatov Institute”
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182
L. V. Ermakova
National Research Center “Kurchatov Institute”
Author for correspondence.
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182
V. V. Dubov
National Research Center “Kurchatov Institute”
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182
D. E. Lelekova
National Research Center “Kurchatov Institute”
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182
R. R. Saifutyarov
National Research Center “Kurchatov Institute”
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182
P. A. Zhdanov
National Research Center “Kurchatov Institute”
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182
M. S. Malozovskaya
National Research Center “Kurchatov Institute”
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182
I. Y. Komendo
National Research Center “Kurchatov Institute”
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182
P. S. Sokolov
National Research Center “Kurchatov Institute”
Email: sokolov-petr@yandex.ru
Russian Federation, Moscow, 123182
A. G. Bondarau
Institute for Nuclear Problems, Belarus State University
Email: ermakova.lydiav@yandex.ru
Belarus, Minsk, 220030
M. V. Korzhik
Institute for Nuclear Problems, Belarus State University
Email: ermakova.lydiav@yandex.ru
Belarus, Minsk, 220030
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