Effect of Phosphorus-Containing Dispersant on the Microstructure and Optical Properties of Scintillation Ceramic (Gd, Y)3(Al, Ga)5O12:Ce with Garnet Structure

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Abstract

Phosphoric acid ester, a typical component of commercial dispersants, affects the functional properties of Gd1.494Y1.494Ce0.012Al2Ga3O12 ceramics. In sintered ceramics, the residual phosphorus can reach up to 40–70% of the introduced amount. The admixture of phosphorus located on the surfaces of the particles activates the grain growth during sintering and leads to the formation of secondary phases of rare-earth phosphates. With increasing phosphorus concentration, the density and optical transmittance of ceramics decrease. Relatively small amount of phosphorus can improve the luminescence properties of ceramics, but large amounts can increase phosphorescence and reduce the scintillation light yield.

About the authors

P. V. Karpyuk

National Research Center “Kurchatov Institute”

Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182

L. V. Ermakova

National Research Center “Kurchatov Institute”

Author for correspondence.
Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182

V. V. Dubov

National Research Center “Kurchatov Institute”

Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182

D. E. Lelekova

National Research Center “Kurchatov Institute”

Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182

R. R. Saifutyarov

National Research Center “Kurchatov Institute”

Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182

P. A. Zhdanov

National Research Center “Kurchatov Institute”

Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182

M. S. Malozovskaya

National Research Center “Kurchatov Institute”

Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182

I. Y. Komendo

National Research Center “Kurchatov Institute”

Email: ermakova.lydiav@yandex.ru
Russian Federation, Moscow, 123182

P. S. Sokolov

National Research Center “Kurchatov Institute”

Email: sokolov-petr@yandex.ru
Russian Federation, Moscow, 123182

A. G. Bondarau

Institute for Nuclear Problems, Belarus State University

Email: ermakova.lydiav@yandex.ru
Belarus, Minsk, 220030

M. V. Korzhik

Institute for Nuclear Problems, Belarus State University

Email: ermakova.lydiav@yandex.ru
Belarus, Minsk, 220030

References

  1. Zhu D., Nikl M., Chewpraditkul W., Li J. // J. Adv. Ceram. 2022. V. 11. № 12. P. 1825. https://doi.org./10.1007/s40145-022-0660-9
  2. Lecoq P., Gektin A., Korzhik M. Inorganic Scintillators for Detector Systems. Physical Principles and Crystal Engineering. Series: Particle Acceleration and Detection. Berlin, Heidelberg: Springer, 2017. https://doi.org./10.1007/978-3-319-45522-8
  3. Bettes B., Xie Y. // Mater. Res. Lett. 2023. V. 11. № 1. P. 1. https://doi.org./10.1080/21663831.2022.2109441
  4. Smyslova V., Kuznetsova D., Bondaray A., Karpyuk P., Korzhik M., Komendo I., Pustovarov V., Retivov V., Tavrunov D. // Photonics. 2023. V. 10. № 10. P. 603. https://doi.org./10.3390/photonics10050603
  5. Retivov V., Dubov V., Komendo I., Karpyuk P., Kuznetsova D., Sokolov P., Talochka Y., Korzhik M. // Nanomaterials. 2022. V. 12. № 23. P. 4295. https://doi.org./10.3390/nano12234295
  6. Hsiue G.H., Chu L.W., Lin I.N. // Colloid Surface. A. 2007. V. 294. № 1–3. P. 212. https://doi.org./10.1016/j.colsurfa.2006.08.013
  7. Caballero A.C., Fernandez J.F., Moure C., Duran P. // Mat. Res. Bull. 1997. V. 32. № 2. P. 221. https://doi.org./10.1016/S0025-5408(96)00179-1
  8. Caballero A.C., Fernandez J.F., Moure C., Duran P. // Mater. Lett. 1998. V. 35. № 1–2. P. 72. https://doi.org./10.1016/S0167-577X(97)00226-7
  9. Caballero A.C., Villegas M., Fernandez J.F., Moure C., Duran P., Florian P., Coutures J.P. // J. Eur. Ceram. Soc. 1999. V. 19. № 6-7. P. 979. https://doi.org./10.1016/S0955-2219(98)00357-4
  10. Caballero A.C., Fernandez J.F., Villegas M., Moure C., Duran P., Florian P., Coutures J.P. // J. Am. Ceram. Soc. 2004. V. 83. № 6. P. 1499. https://doi.org./10.1111/j.1151-2916.2000.tb01417.x
  11. Wang X.-H., Gui Z.-L., Li L.-T. // Mater. Chem. Phys. 1998. V. 55. № 3. P. 193. https://doi.org./10.1016/S0254-0584(98)00120-5
  12. Celi L.A., Caballero A.C., Villegas M., Eiras J.A., Moure C., Fernandez J.F. // Bol. Soc. Esp. Cerám. Vidrio. 2001. V. 40. № 2. P. 119. https://doi.org./10.3989/cyv.2001.v40.i2.752
  13. De Camargo I.L., Erbereli R., Fortulan C.A. // J. Eur. Ceram. Soc. 2021. V. 41. № 14. P. 7182. https://doi.org./10.1016/j.jeurceramsoc.2021.07.005
  14. Chang S.-M., Hur S., Park J., Lee D.-G., Shin J., Kim H.S., Song S.E., Baik J.M., Kim M., Song H.-C., Kang C.-Y. // Addit. Manuf. 2023. V. 67. P. 103470. https://doi.org./10.1016/j.addma.2023.103470
  15. Kim J., Choi Y.J., Gal C.W., Park H., Yoon S.-Y., Yun H.-S. // Int. J. Appl. Ceram. Technol. 2021. V. 19. № 2. P. 968. https://doi.org./10.1111/ijac.13965
  16. Kim I., Kim S., Andreu A., Kim J.-H., Yoon Y.-L. // Addit. Manuf. 2022. V. 52. P. 102659. https://doi.org./10.1016/j.addma.2022.102659
  17. Kovacev N., Li S., Li W., Zeraati-Rezaei S., Tsolakis A., Essa K. // Aerospace. 2022. V. 9. № 5. P. 255. https://doi.org./10.3390/aerospace9050255
  18. Zhang S., Sutejo I.A., Kim J., Choi Y.J., Gal C.W., Yun H. // Ceramics. 2022. V. 5. № 3. P. 562. https://doi.org./10.3390/ceramics5030042
  19. Ермакова Л.В., Кузнецова Д.Е., Смыслова В.Г., Соколов П.С., Досовицкий Г.А., Чижевская С.В. // Новые огнеупоры. 2022. № 10. С. 45. https://doi.org./10.17073/1683-4518-2022-10-45-50
  20. Ermakova L.V., Dubov V.V., Saifutyarov R.R., Kuznetsova D.E., Malozovskaya M.S., Karpyuk P.V., Dosovitskiy G.A., Sokolov P.S. // Ceramics. 2023. V. 6. № 1. P. 43. https://doi.org./10.3390/ceramics6010004
  21. Dubov D., Gogoleva M., Saifutyarov R., Kucherov O., Korzhik M., Kuznetsova D., Komendo I., Sokolov P. // Photonics. 2023. V. 10. № 1. P. 54. https://doi.org./10.3390/photonics10010054
  22. Ermakova L.V., Smyslova V.G., Dubov V.V., Kuznetsova D.E., Malozovskaya M.S., Saifutyarov R.R., Karpyuk P.V., Sokolov P.S., Komendo I.Yu., Bondarau A.G., Mechinsky V.A., Korzhik M.V. // Ceramics. 2023. V. 6. № 3. P. 1478. https://doi.org./10.3390/ceramics6030091
  23. Korzhik M., Borisevich A., Fedorov A., Gordienko E., Karpyuk P., Dubov V., Sokolov P., Mikhlin A., Dosovitskiy G., Mechinsky V., Kozlov D., Uglov V. // J. Lumin. 2021. V. 234. P. 117933. https://doi.org./10.1016/j.jlumin.2021.117933
  24. Gordienko E., Fedorov A., Radiuk E., Mechinsky V., Dosovitskiy G., Vashchenkova E., Kuznetsova D., Retivov V., Dosovitskiy A., Korjik M., Sandu R. // Opt. Mater. 2018. V. 78. P. 312. https://doi.org./10.1016/j.optmat.2018.02.045
  25. Федоров А.А., Дубов В.В., Ермакова Л.В., Бондарев А.Г., Карпюк П.В., Коржик М.В., Кузнецова Д.Е., Мечинский В.А., Смыслова В.Г., Досовицкий Г.А., Соколов П.С. // Приборы и техника эксперимента. 2023. № 2. С. 52. https://doi.org./10.31857/S0032816223010159
  26. Retivov V., Dubov V., Kuznetsova D., Ismagulov A., Korzhik M. // J. Rare Earth. 2023. V. 41. № 12. P. 1911. https://doi.org./10.1016/j.jre.2022.09.018

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