No 6 (2024)
Biotechnology
LED cultivated Eruca sativa morphogenesis and productivity in different soil mixtures
Abstract
The main purpose of work was to assess how different soil mixtures could affect the productivity of plants with other conditions being equal and find the most productive treatment. The other purpose was to show that the addition of fertilizer could be more efficient in comparison with hydroponics methods. The methods used in this work include LEDs light sources development, morphometric parameters estimation, and statistical analysis. In our research, we used mixtures based on universal soil, sand, sapropel and the Zion universal ion-exchange nutrient substrate in various proportions. 100% soil was used as a control. The plants were grown under white light (WW) with an intensity of 300 μmol m-2 s-1 and RGB range percent ratio R33:G41:B26. Results. The highest values of fresh weight, total leaf area, and plant leaves number were achieved under the Soil + Zion conditions, respectively. Under the Soil + Sand + Zion and Soil + Zion conditions, the total leaf area, wet weight and leaves number were increased in comparison with the control. The highest productivity was reached in the Soil + Zion experiment. The results demonstrated that the use of a universal ion-exchange nutrient substrate resulted in improved performance in most of the experimental mixtures in comparison with other experiments and control. Soil mixtures with ion-exchange nutrient substrates has advantages to other soil mixtures and can be used to optimize the quality and timing of plant growth.



Plants low-frequency acoustic response to abiotic stress
Abstract
In the paper acoustic microvibrations in the range from 0.1 to 27 Hz that occur in the leaves and root system of the Chinese rose plant in response to light irradiation, as well as damage to the leaves in the form of applying the irritating ointment “Linkus” to them. It has been shown that when a plant is irradiated with light, microvibrations arise in the leaf with a frequency of 5.77198 Hz, which presumably can be associated with the process of photosynthesis. When exposed to light, microvibrations were also recorded in the root system with frequencies of 23.61 and 16.35 Hz. Applying irritating ointment “Linkus” to four spatially spaced rose leaves also led to the appearance of characteristic microvibrations in the root system, with each leaf corresponding to its own vibration frequency, which apparently indicates that the rhizome receives information about each leaf and thus, using low-frequency microvibrations, the plant can interact with the external environment.



Chemical Sciences. Functional Coatings
Recent advances in the creation of antibacterial coatings on titanium materials based on the PEO method
Abstract
Currently, one of the significant problems associated with implant materials, including orthopedic metal implants, are implant-associated infections. This disease can lead not only to the need for systemic treatment, but also to repeated operations and, in the most negative cases, to death. One of the effective strategies to eliminate such infections is the creation of antibacterial surface layers. In recent years, the attention of researchers around the world has been focused on the creation of such structures. This review presents the results of the latest achievements in the field of plasma electrolytic synthesis of surface layers with a pronounced antibacterial effect. The main existing approaches to solving such problems are described, as well as their advantages and disadvantages, and future directions in this field are outlined.



Hybrid coatings with a self-healing effect on the surface of functional materials
Abstract
This article provides a review of advances in self-healing hybrid coatings development used to protect functional materials in corrosive environments.Self-healing coatings are currently attracting much interest due to their ability to suppress corrosion, which is a serious problem in almost all industries. The design of smart coatings with the active anticorrosion protection and self-healing is necessary for the long-term service life of metal structures in aggressive environments. When a self-healing coating is damaged in a corrosive media a new protective layer is formed on the surface of the defect and the functional characteristics of the product are restored. Autonomous mechanisms for restoring the protective properties of anticorrosion layers activated due to introducing corrosion inhibitors into the coating matrix.



Antifouling coatings on the base of bioinspired technologies for marine applications
Abstract
In the offshore industry, antifouling protection is achieved mainly through the use of special antifouling coatings whose polymer matrix contains biocides releasing during the object exploitation at a controlled rate. Despite its recognized efficiency, this strategy has significant drawbacks, among which is the high ecotoxicity of antifouling agents. The increasing legislation on the use of antifouling compounds has intensified efforts to find alternative ecologically friendly technologies. Antifouling strategies possessed by living organisms are of particular scientific interest. This paper presents an overview in the field of bioinspired technologies applicable to the development of antifouling coatings in the marine application.



Physico-chemical aspects and the mechanism of formation of anti-icing coatings for aircraft structures
Abstract
The review analyzes literature sources describing methods and approaches to the creation of anti-icing coatings, as well as the problems of development and application of new anti-icing materials and coatings. The existing works presenting the results of research into the characteristics of superhydrophobic/anti-icing coatings on the surface of metals and alloys treated by plasma electrolytic oxidation are presented.



Embedding of magnetoactive particles from slurry electrolytes into PEO coatings on titanium
Abstract
The paper summarizes the literature data on plasma electrolytic treatment of titanium in electrolytes with dispersed magnetoactive particles in order to form surface structures with certain magnetic properties. The compositions of electrolytes, process parameters and magnetic properties of the resulting coatings are presented. Depending on the chemical nature and characteristics of the particles, an inert or reactive mechanism of their introduction from the electrolyte into the growing coatingsis carried out. It is shown that metal oxide particles located on the surface, mainly in pores, and in the coating bulk make the main contribution to the magnetic properties of the samples. By changing the electrolyte formula and the concentration of components, it is possible to control the composition of the particles and, accordingly, the magnetic characteristics of the coating.



Chemical sciences. Sorption processes and materials
Inorganic sorbents for water purification from petroleum products based on mineral and technogenic raw materials: production, application, regeneration
Abstract
The article presents a review of the main trends in the development of sorption methods for cleaning water bodies from oil and oil products using mineral sorbents. Based on an analysis of literature data primarily from the last two decades, including the results of their own research by the authors, natural and artificial sorbents and their modifications are described. Methods and devices for obtaining sorption materials, features of their practical application, and the results of studying their basic properties are considered. The need to develop methods for regenerating spent sorbents is substantiated. The prospects for using mineral materials of natural and technogenic origin as a basis for creating new effective oil product sorbents are shown.



Modeling of sorption equilibria: state of the art and prospects of models development for heterogeneous sorbents
Abstract
For many years, adsorption remains one of the most universal and cost-effective approaches to purifying waters of various compositions and extracting valuable components from technological solutions. In addition to affinity, selectivity, and high sorption capacity, the kinetic characteristics of sorbents are of great importance, since they determine the productivity of both industrial sorption columns and small point-of-use filters operating at high flow rates. This review discusses the current state of the art in modeling sorption dynamics and a new approach to analysis of sorption equilibria using the model of sorption/desorption rate constants distribution (RCD) for heterogeneous sorbents developed at the Institute of Crystallography FEB RAS for predictive modeling of breakthrough curves based on the kinetic parameters of sorption centers (RCD functions) calculated from experimental data obtained under static conditions. Using as the example supermacroporous sorbents based on polyethyleneimine, it was shown how the RCD model and its variants, which take into account diffusion limitations and the presence of complexing agents, can be used to optimize conditions for the metal ions concentration and separation under dynamic conditions.



Chitosan-based composite materials – sorbents for the purification of liquid radioactive waste
Abstract
The approaches to production of chitosan-containing composites designed to remove radionuclides from aqueous solutions were considered in this review. Methods for obtaining chitosan-based sorbents for the removal of metals, the main sources of radioactive contamination (U, Sr, Cs), are described. The efficiency of using a biopolymer for these purposes is significantly increased as a result of physical or chemical modification, as well as the introduction of inorganic fillers. From the sorbents which were considered, the cheapest and most effective Sr and Cs materials for sorption are highlighted and simplified schemes for their production are given. The main purpose of this review is to provide up-to-date information on the most important properties of composites in combination with inorganic fillers and to show their advantages as sorbents in the purification of contaminated aqueous solutions.



Chemical sciences. Advanced inorganic materials
Structure, NMR spectra, ionic mobility and phase transitions in complex fluoride zirconates
Abstract
The brief review presents the results of ion-transport properties studies of zirconium fluoride complexes with alkali cations and ammonium. The relationship between the structure (dimensionality) of the compound, the degree of doping and the nature of the dopant metal, the presence and nature of phase transitions, the shape of the NMR spectra, ionic mobility and conductivity of these compounds is considered.



New glasses in the MNbOF5-BaF2-InF3 (M–Mn, Cd, Zn) systems
Abstract
The article summarizes the results of studying new glasses in the MnNbOF5-BaF2-InF3, ZnNbOF5-BaF2-InF3 and CdNbOF5-BaF2-InF3 systems. The thermal characteristics of glasses were studied, the role of fluorindate and fluoroniobate components in glass formation and crystallization behavior was revealed. Glasses in the MNbOF5-BaF2-InF3 systems can be considered three-component; their structure is formed by polyhedra of fluoroniobate (NbO2F4 and NbO3F3), InF6 and polyhedra formed by MFn. The possibility of obtaining glass ceramics has been demonstrated. For glasses in the CdNbOF5-BaF2-InF3 and ZnNbOF5-BaF2-InF3 systems, the photoluminescence was detected corresponding to emission levels of 542, 573 and 673, 751 nm, depending on the presence and concentration of indium trifluoride in the glass. Luminescent properties are shown only by glasses in which nanoparticles, 9–13 nm, were detected according to SAXS data.


